Spot-resolved analysis is required to characterize the heterogeneity of solid materials, which can be done with a number of techniques (Fig. 1). By means of Laser ablation, coupled with various detectors (Fig. 2), spatially resolved analysis in the range of microns is feasible in a few seconds. No special sample preparation is needed, and results are available within minutes. The sample is directly ablated by the laser, and in LIBS (Laser-Induced Breakdown Spectroscopy) the generated plasma-radiation is spectrographically analyzed; the ablated material, transported by a carrier gas, is analyzed by ICP-MS (plasma mass spectrometry) or ICP-OES (plasma emission spectrometry) to achieve trace-level detection power and isotopic resolution. Compared to electron beam techniques, where heavy sample preparation is necessary, and limits of detection as low as part per million are not possible, laser microanalysis is a significant progress. Plus depth-profiling analysis can be done over larger thicknesses of tens of microns, with nano-scale depth resolution.
We elaborated and further developed our laser microanalysis setup to measure in an automated and efficient way the largest possible element menu. To extend the specific analysis capabilities, detection via ICP-MS, ICP-OES and LIBS system is being integrated within a single system. Out “MATLAS" multi-spectroscopy system enable the analysis for a wide range of elements and materials, from metal to ceramic till polymers and biological samples, within a single laser shot. Finally, we have self-developed an extreme ultraviolet (EUV) laser with wavelength of 10-50nm, to radically enhance the analytical capabilities. The latter permits direct ionization without a secondary ionization source, e.g. ICP.
- Bleiner, Davide, Libor Juha, and Di Qu. "Soft X-ray laser ablation for nano-scale chemical mapping microanalysis." Journal of Analytical Atomic Spectrometry 35.6 (2020): 1051-1070.
- Bleiner, D., Trottmann, M., Cabas-Vidani, A., Wichser, A., Romanyuk, Y. E., & Tiwari, A. N. (2020). XUV laser mass spectrometry for nano-scale 3D elemental profiling of functional thin films. Applied Physics A: Materials Science and Processing, 126, 230 (10 pp.). https://doi.org/10.1007/s00339-020-3381-3
- Arbelo, Y., & Bleiner, D. (2019). Tabletop extreme ultraviolet time‐of‐flight spectrometry for trace analysis of high ionization energy samples. Rapid Communications in Mass Spectrometry, 33(14), 1196-1206. https://doi.org/10.1002/rcm.8463
- Bleiner, D., Rush, L. A., Rocca, J. J., & Menoni, C. S. (2019). Rapid 3D chemical visualization with tabletop XUV laser mass spectrometry. In A. Klisnick & C. S. Menoni (Eds.), Proceedings of SPIE: Vol. 11111. X-ray lasers and coherent X-ray sources: development and applications XIII (p. 1111107 (10 pp.). https://doi.org/10.1117/12.2528160