Laboratory for High Performance Ceramics

 

Head of Laboratory

Dr. Jakob Schwiedrzik

 

Assistance and Support

Georgiana Schönberg
Dipl. Ing. Laura Conti
Roland Bächtold

 

Ceramic based composites

 

Dr. Gurdial Blugan

 

Smart ceramic processing

 

Dr. Frank Clemens

 

Nanopowders and ceramics

 

Dr. Michael Stuer

 

Ceramic electrodes and electrolytes

Dr. Artur Braun

 

Architectured Materials

 

Dr. Jakob Schwiedrzik

Scientists:

Dr. Camila P. Canales
Dr. Stefan Heinen
Dr. Heloisa Ramlow

Dr. Thamanna Thakur





PhD Students:

Dipesh K. Dubey
Karol Kuglarz
Dagmara Uhl

 

Scientists:

Dr. Arun Ichangi
Dr. Elham Montakhab







PhD Students:

Christopher Bascucci
Sofiia Butenko

 

Scientists:

Dr. Marc Brunet-Cabre
Dr. Nick Goossens
Dr. Connor Firth
Dr. Amy J. Knorpp
Dr. Isacco Mazo
Dr. Rishabh Shukla
Dr. Enrico Storti
Dr. Romain Trihan

​​​PhD Students:

Annalena Erlacher
Katerina Urbancova


 

 

 

Scientists:

Dr. Alexey Rulev
Dr. Nikolay Ryzhkov

 

 

Scientists:

Dr. Kevin Both
Dr. Christian Minnert
Dipl. Ing. Martin J. De Oliveira






PhD Students:

Martina Birocco
Corentin Foucher
Valeria Zanrè


 

 


Nanopowders and ceramics

Within the scope to use materials and energy ressources in the most sustainable manner, attention is put on advanced morphological, chemical and crystallographic characteristics of ceramic powders, materials and composites. Special focus is put on the multidimensional space, beyond density and grain size, and the resulting effects on the materials properties with the aim to tend towards advanced microstructure and grain boundary engineering.

Powder synthesis

Among our competences is the synthesis of functional oxide nanoparticles (by flame processes), their characterisation and processing.

Powders can be used as fillers in polymer composites and coatings, or serve as a starting material for advanced ceramic components. Hereby special focus is put on the particles characteristics such as their shape, size and phase with the purpose to enable the development of materials with new or improved properties. Engineered quality powders are key to achieve innovation with the best performance and added-value of the materials.

We perform R&D collaborations in the frame of national and international projects with partners from industry and university.

Three-dimensional shaping of ceramics

Driven by the remaining challenges in the additive manufacturing field, light-based ceramic shaping is another competence area. Studying the whole process chain, special focus is put into into powder feedstock preparation and slurry formulation. Our goals are not only to shape ceramic parts - and the future - but do so expanding and optimizing their properties.

Current research example:

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Niro Spray Dryer
Selective Laser Sintering and Melting

Shaping of complex shaped, high precision and reliable parts as well as the long processing time and cost-intensive post processing is a key challenge in ceramics processing. Selective laser melting could be a solution of these problems. Although it is already a well-controlled and extensively used technology in the field of metals, alloys and polymers, key problems still have to be resolved for its use on brittle materials, and especially high performance ceramics.

The inability to closely monitor and fine tune the interaction of laser light sources with ceramic based powders remains a problem. Combined with the slow sintering kinetics of ceramics, a whole research field is left to explore. This highlights the current absence of industrial SLS processes to consolidate ceramic powders into dense structures with controlled material properties.

In our research, nanosized ceramic powders are granulated by spray drying to improve the powder handling especially from a flowability and safety point of view. Focus is put on maximizing the powder bed packing density and its influence on the solid and liquid phase sintering. Furthermore, the influence of the composition and morphology of these composite granules on the light absorption is studied, which in addition to minimizing thermal stresses and cracks is a key challenge for the future.

Ceramic based filters and membranes

Filters and membranes play an increasingly important role for technological breakthroughs bringing environmental, societal and economic value. Among other materials, ceramic based ones are in this field important because of their specific properties such as heat or chemical resistance. Hereby we focus in particular on the advanced microstructural control via powder selection and processing as well as advanced doping and sintering strategies.

Current research example: Virus Filtration applying surface modified ceramics and carbon nanotubes

Water purification is necessary to prevent the spread of different diseases, caused by water-borne germs like bacteria, protozoa, and viruses. The germs may be separated from the water by a physical process, where the contaminated water is passing a porous medium like a filter or by adsorption driven separation processes. Our projects are focused on the adsorption based separation of viruses from water applying nanostructured, ceramic based filters as well as modified nanofibers originating from carbon nanotubes CNT and graphene. The biggest challenge results from the required filtering scale, namely the size of the viruses 20-50 times smaller than bacteria.

Recently we could evaluate the application of surface modified ceramic water filters for virus removal. Virus separation efficiencies (MS 2 bacteriophages and PhiX 174 bacteriophages ; size 25 nm, PZC 2 and 7 respectively) of 99 % to 99.99 % could be achieved. Such efficiencies being limited to narrow pH conditions more research is necessary to improve the systems to be compatible with common water sources. Modification of the highly active, porous ceramic surface was achieved by incorporation of nanosized inorganic particles.

As an alternative and promising solution for a broad pH spectrum, we apply CNT based fibers, after modification of the nanostructured surface.

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Size of different types of viruses in comparison to E coli bacterium (schematic view)

Smart ceramic processing

The focal point of the tasks lies in the interdisciplinary collaboration in the production of functional materials and composites. Developing prototypes of fibres, hollow fibers, foils and tubes is the main focus in the process development for developing novel system components.

> An overview of Smart Processing for Ceramics and Sensor-Composite Materials you find here:
Overview-PDF (982KB)

Thermoplastic forming Ceramics

The Laboratory for High Performance Ceramics is engaged in the development of thermoplastic forming and the development of thermoplastic binder systems for pressing, extrusion, injection molding, dip coating and 3D printing of ceramic components. Due to its many years of experience, the group does not focus on a specific binder system, but rather develops and optimizes customer-oriented, individual solutions. In the course of these developments, binder systems for the thermoplastic 3D printing of ceramic powders are also being developed. The additive manufacturing process of thermoplastic composites (Fused Deposition Modeling - FDM or Fused Filament Fabrication - FFF) is a recognized and widespread technology for the production of complex macroscopic structures. Empa develops thermoplastic binder systems, which enable cost-effective printing of ceramic components with conventional (open-source) FDM printers. Figure 1 shows the most important factors that influence the 3D printing of ceramics.



Figure 1: Typical factors influencing thermoplastic 3D printing of ceramic materials
blue = machine factors,
red = material failures

 

The 3D printing of thermoplastic ceramics offers the possibility to produce components individually via layered deposition. Typically, thermoplastic filaments are fed into a heated nozzle via a Bowden extruder. The polymer binder is melted and deposited in a desired position. After cooling and hardening, a structure with a layer thickness between 0.03 and 1.2 mm can built up.

The process is divided into several production steps:

  1. Compounding of the ceramic powder and the thermoplastic binder
  2. Filament or granule production for thermoplastic 3D printing
  3. 3D printing by melting the filament and layered deposition of the material
  4. Thermal treatment (debinding and sintering of the components)

 

Post-treatment of the component surface can be done on the printed, debinded or sintered state. Figure 2 shows a commercially available simple 3D printer used for materials development.

 

Figure 2: Commercially available 3D printer for the development of thermoplastic ceramic materials.


Ceramic-based Composites

We design, process and characterize ceramic based composites for innovative and challenging structural and functional applications. Projects are the center of attention, in which

  • ceramic-ceramic composites (CMC),
  • micro and macro layered structures (laminates),
  • polymer derived ceramic composites (PDC),
  • coatings,
  • graded materials (FGM) and
  • ceramics joined to metals

are required. We develop new and optimize state of the art production routes and transfer know-how and technologies to industry.

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Teaching Activities

 

Dr. Johann Jakob Schwiedrzik

  • ETH Zürich,  Orthopaedic Biomechanics, HEST
  • EPF Lausanne, Thin Film and Small Scale Mechanics, EDMX

 

 

 

Dr. Frank Clemens

  • ETH Zürich, Advanced Composites 
  • ETH Zürich, Adaptive Material Systems

 

 

Dr. Michael Stuer

  • EPF Lausanne, Ingénierie des matériaux II (MSE-215)
  • EPF Lausanne, Advanced ceramic technologies (MSE-495)