Publications 2020

Aebli, M.; Piveteau, L.; Nazarenko, O.; Benin, B. M.; Krieg, F.; Verel, R.; Kovalenko, M. V. Lead-halide scalar couplings in 207Pb NMR of APbX3 perovskites (A = Cs, methylammonium, formamidinium; X = Cl, Br, I). Sci. Rep. 2020, 10 (1), 8229 (9 pp.). https://doi.org/10.1038/s41598-020-65071-4
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Aebli, M.; Benin, B. M.; McCall, K. M.; Morad, V.; Thöny, D.; Grützmacher, H.; Kovalenko, M. V. White CsPbBr3: characterizing the one-dimensional cesium lead bromide polymorph. Helv. Chim. Acta 2020, 103 (7), e2000080 (8 pp.). https://doi.org/10.1002/hlca.202000080
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Athanasiou, M.; Papagiorgis, P.; Manoli, A.; Bernasconi, C.; Poyiatzis, N.; Coulon, P. M.; Shields, P.; Bodnarchuk, M. I.; Kovalenko, M. V.; Wang, T.; et al. InGaN nanohole arrays  coated by lead halide perovskite nanocrystals for solid-state lighting. ACS Appl. Nano Mater. 2020, 3 (3), 2167-2175. https://doi.org/10.1021/acsanm.9b02154
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Barrutia, L.; García, I.; Barrigón, E.; Ochoa, M.; Algora, C.; Rey-Stolle, I. Impact of the III-V/Ge nucleation routine on the performance of high efficiency multijunction solar cells. Sol. Energy Mater. Sol. Cells 2020, 207, 110355 (7 pp.). https://doi.org/10.1016/j.solmat.2019.110355
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Benin, B. M.; McCall, K. M.; Wörle, M.; Morad, V.; Aebli, M.; Yakunin, S.; Shynkarenko, Y.; Kovalenko, M. V. The Rb7Bi3-3xSb3xCl16 family: a fully inorganic solid solution with room-temperature luminescent members. Angew. Chem. Int. Ed. 2020, 59, 14490-14497. https://doi.org/10.1002/anie.202003822
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Bleiner, D.; Trottmann, M.; Müller, R.; Rush, L.; Kuznezov, I.; Cabas-Vidani, A.; Romanyuk, Y.; Tiwari, A.; Patzke, G. R.; Menoni, C. S.; et al. 3D chemical mapping of thin films by means of X-ray laser microanalysis. In X-ray lasers 2018. Proceedings of the 16th international conference on X-ray lasers, presented at the 16th international conference on X-ray lasers (ICXRL 2018), Prague, Czech Republic, October 7-12, 2018; Kozlová, M., Nejdl, J., Eds.; Springer proceedings in physics; Springer: Cham, 2020; Vol. 241, pp 3-10. https://doi.org/10.1007/978-3-030-35453-4_1
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Bleiner, D.; Trottmann, M.; Cabas-Vidani, A.; Wichser, A.; Romanyuk, Y. E.; Tiwari, A. N. XUV laser mass spectrometry for nano-scale 3D elemental profiling of functional thin films. Appl. Phys. A 2020, 126, 230 (10 pp.). https://doi.org/10.1007/s00339-020-3381-3
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Bolat, S.; Torres Sevilla, G.; Mancinelli, A.; Gilshtein, E.; Sastre, J.; Cabas Vidani, A.; Bachmann, D.; Shorubalko, I.; Briand, D.; Tiwari, A. N.; et al. Synaptic transistors with aluminum oxide dielectrics enabling full audio frequency range signal processing. Sci. Rep. 2020, 10, 16664 (8 pp.). https://doi.org/10.1038/s41598-020-73705-w
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Bombsch, J.; Avancini, E.; Carron, R.; Handick, E.; Garcia-Diez, R.; Hartmann, C.; Félix, R.; Ueda, S.; Wilks, R. G.; Bär, M. NaF/RbF-treated Cu(In,Ga)Se2 thin-film solar cell absorbers: distinct surface modifications caused by two different types of rubidium chemistry. ACS Appl. Mater. Interfaces 2020, 12 (31), 34941-34948. https://doi.org/10.1021/acsami.0c08794
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Cadilha Marques, G.; Sukuramsyah, A. M.; Arnal, A.; Bolat, S.; Aribia, A.; Feng, X.; Singaraju, S. A.; Ramon, E.; Romanyuk, Y.; Tahoori, M.; et al. Fabrication and modeling of pn-diodes based on inkjet printed oxide semiconductors. IEEE Electr. Device Lett. 2020, 41 (1), 187-190. https://doi.org/10.1109/LED.2019.2956346
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Dubey, R. J. C.; Sasikumar, P. V. W.; Cerboni, N.; Aebli, M.; Krumeich, F.; Blugan, G.; Kravchyk, K. V.; Graule, T.; Kovalenko, M. V. Silicon oxycarbide-antimony nanocomposites for high-performance Li-ion battery anodes. Nanoscale 2020, 12 (25), 13540-13547. https://doi.org/10.1039/D0NR02930K
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Dubey, R.; Gimpel, A.; Zouboulis, K.; Böcker, M. Striving for an optimal entry into the chemical & pharmaceutical job market. Chimia 2020, 74 (9), 737-738. https://doi.org/10.2533/chimia.2020.737
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Dörner, L.; Schmutz, P.; Kägi, R.; Kovalenko, M. V.; Jeurgens, L. P. H. Electrophoretic deposition of nanoporous oxide coatings from concentrated CuO nanoparticle dispersions. Langmuir 2020, 36 (28), 8075-8085. https://doi.org/10.1021/acs.langmuir.0c00720
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Dörner, L. E. Highly energetic Al/CuO thermite coatings through nanoparticle composites. Doctoral dissertation, ETH Zürich, Zürich, Switzerland, 2020, 152 p.
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Gilshtein, E.; Bolat, S.; Sevilla, G. T.; Cabas-Vidani, A.; Clemens, F.; Graule, T.; Tiwari, A. N.; Romanyuk, Y. E. Inkjet-printed conductive ITO patterns for transparent security systems. Adv. Mater. Technol. 2020. https://doi.org/10.1002/admt.202000369
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Groeneveld, B. G. H. M.; Adjokatse, S.; Nazarenko, O.; Fang, H. H.; Blake, G. R.; Portale, G.; Duim, H.; ten Brink, G. H.; Kovalenko, M. V.; Loi, M. A. Stable cesium formamidinium lead halide perovskites: a comparison of photophysics and phase purity in thin films and single crystals. Energy Technol. 2020, 8 (4), 1901041 (7 pp.). https://doi.org/10.1002/ente.201901041
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Hopper, T. R.; Gorodetsky, A.; Jeong, A.; Krieg, F.; Bodnarchuk, M. I.; Maimaris, M.; Chaplain, M.; Macdonald, T. J.; Huang, X.; Lovrincic, R.; et al. Hot carrier dynamics in perovskite nanocrystal solids: role of the cold carriers, nanoconfinement, and the surface. Nano Lett. 2020, 20 (4), 2271-2278. https://doi.org/10.1021/acs.nanolett.9b04491
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Hopper, T. R.; Jeong, A.; Gorodetsky, A. A.; Krieg, F.; Bodnarchuk, M. I.; Huang, X.; Lovrincic, R.; Kovalenko, M. V.; Bakulin, A. A. Kinetic modelling of intraband carrier relaxation in bulk and nanocrystalline lead-halide perovskites. Phys. Chem. Chem. Phys. 2020, 22 (31), 17605-17611. https://doi.org/10.1039/d0cp01599g
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Hou, L.; Zhao, C.; Yuan, X.; Zhao, J.; Krieg, F.; Tamarat, P.; Kovalenko, M. V.; Guo, C.; Lounis, B. Memories in the photoluminescence intermittency of single cesium lead bromide nanocrystals. Nanoscale 2020, 12 (12), 6795-6802. https://doi.org/10.1039/d0nr00633e
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Huang, C. S.; Jakubowski, K.; Ulrich, S.; Yakunin, S.; Clerc, M.; Toncelli, C.; Rossi, R. M.; Kovalenko, M. V.; Boesel, L. F. Nano-domains assisted energy transfer in amphiphilic polymer conetworks for wearable luminescent solar concentrators. Nano Energy 2020, 76, 105039 (8 pp.). https://doi.org/10.1016/j.nanoen.2020.105039
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Ibaceta-Jaña, J.; Muydinov, R.; Rosado, P.; Mirhosseini, H.; Chugh, M.; Nazarenko, O.; Dirin, D. N.; Heinrich, D.; Wagner, M. R.; Kühne, T. D.; et al. Vibrational dynamics in lead halide hybrid perovskites investigated by Raman spectroscopy. Phys. Chem. Chem. Phys. 2020, 22 (10), 5604-5614. https://doi.org/10.1039/c9cp06568g
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Jiang, Y.; Feurer, T.; Carron, R.; Torres Sevilla, G.; Moser, T.; Pisoni, S.; Erni, R.; Rossell, M. D.; Ochoa, M.; Hertwig, R.; et al. High-mobility In2O3:H electrodes for four-terminal perovskite/CuInSe2 tandem solar cells. ACS Nano 2020, 14 (6), 7502-7512. https://doi.org/10.1021/acsnano.0c03265
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Jiang, Y.; Yang, S. C.; Jeangros, Q.; Pisoni, S.; Moser, T.; Buecheler, S.; Tiwari, A. N.; Fu, F. Mitigation of vacuum and illumination-induced degradation in perovskite solar cells by structure engineering. Joule 2020, 4 (5), 1087-1103. https://doi.org/10.1016/j.joule.2020.03.017
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Kahmann, S.; Nazarenko, O.; Shao, S.; Hordiichuk, O.; Kepenekian, M.; Even, J.; Kovalenko, M. V.; Blake, G. R.; Loi, M. A. Negative thermal quenching in FASnI3 perovskite single crystals and thin films. ACS Energy Lett. 2020, 5 (8), 2512-2519. https://doi.org/10.1021/acsenergylett.0c01166
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Kothandaraman, R. K.; Jiang, Y.; Feurer, T.; Tiwari, A. N.; Fu, F. Near-infrared-transparent perovskite solar cells and perovskite-based tandem photovoltaics. Small Methods 2020, 4 (10), 2000395 (56 pp.). https://doi.org/10.1002/smtd.202000395
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Kravchyk, K. V.; Kovalenko, M. V. Aluminum electrolytes for Al dual-ion batteries. Communications Chem. 2020, 3, 120 (9 pp.). https://doi.org/10.1038/s42004-020-00365-2
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Kravchyk, K. V.; Kovalenko, M. V. Building better dual-ion batteries. MRS Energy Sustain.: Rev. J. 2020, 7, e36 (7 pp.). https://doi.org/10.1557/mre.2020.38
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Kravchyk, K. V.; Kovalenko, M. V.; Bodnarchuk, M. I. Colloidal antimony sulfide nanoparticles as a high-performance anode material for Li-ion and Na-ion batteries. Sci. Rep. 2020, 10 (1), 2554 (8 pp.). https://doi.org/10.1038/s41598-020-59512-3
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Kravchyk, K. V.; Seno, C.; Kovalenko, M. V. Limitations of chloroaluminate ionic liquid anolytes for aluminum-graphite dual-ion batteries. ACS Energy Lett. 2020, 5 (2), 545-549. https://doi.org/10.1021/acsenergylett.9b02832
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Kravchyk, K. V.; Kovalenko, M. V. The pitfalls in nonaqueous electrochemistry of Al-ion and Al dual-ion batteries. Adv. Energy Mater. 2020. https://doi.org/10.1002/aenm.202002151
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Lignos, I.; Maceiczyk, R. M.; Kovalenko, M. V.; Stavrakis, S. Tracking the fluorescence lifetimes of cesium lead halide perovskite nanocrystals during their synthesis using a fully automated optofluidic platform. Chem. Mater. 2020, 32 (1), 27-37. https://doi.org/10.1021/acs.chemmater.9b03438
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Lu, H.; Liu, Y.; Ahlawat, P.; Mishra, A.; Tress, W. R.; Eickemeyer, F. T.; Yang, Y.; Fu, F.; Wang, Z.; Avalos, C. E.; et al. Vapor-assisted deposition of highly efficient, stable black-phase FAPbI3 perovskite solar cells. Science 2020, 370 (6512), eabb8985 (8 pp.). https://doi.org/10.1126/science.abb8985
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McCall, K. M.; Morad, V.; Benin, B. M.; Kovalenko, M. V. Efficient lone-pair-driven luminescence: structure-property relationships in emissive 5s2 metal halides. ACS Mater. Letters 2020, 2 (9), 1218-1232. https://doi.org/10.1021/acsmaterialslett.0c00211
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McCall, K. M.; Sakhatskyi, K.; Lehmann, E.; Walfort, B.; Losko, A. S.; Montanarella, F.; Bodnarchuk, M. I.; Krieg, F.; Kelestemur, Y.; Mannes, D.; et al. Fast neutron imaging with semiconductor nanocrystal scintillators. ACS Nano 2020. https://doi.org/10.1021/acsnano.0c06381
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Miranti, R.; Septianto, R. D.; Ibáñez, M.; Kovalenko, M. V.; Matsushita, N.; Iwasa, Y.; Bisri, S. Z. Electron transport in iodide-capped core@shell PbTe@PbS colloidal nanocrystal solids. Appl. Phys. Lett. 2020, 117 (17), 173101 (6 pp.). https://doi.org/10.1063/5.0025965
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Miranti, R.; Shin, D.; Septianto, R. D.; Ibáñez, M.; Kovalenko, M. V.; Matsushita, N.; Iwasa, Y.; Bisri, S. Z. Exclusive electron transport in core@shell PbTe@PbS colloidal semiconductor nanocrystal assemblies. ACS Nano 2020, 14 (3), 3242-3250. https://doi.org/10.1021/acsnano.9b08687
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Morad, V.; Yakunin, S.; Kovalenko, M. V. Supramolecular approach for fine-tuning of the bright luminescence from zero-dimensional antimony(III) halides. ACS Mater. Letters 2020, 2 (7), 845-852. https://doi.org/10.1021/acsmaterialslett.0c00174
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Moser, T.; Artuk, K.; Jiang, Y.; Feurer, T.; Gilshtein, E.; Tiwari, A. N.; Fu, F. Revealing the perovskite formation kinetics during chemical vapour deposition. J. Mater. Chem. A 2020, 8 (42), 21973-21982. https://doi.org/10.1039/D0TA04501B
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Motti, S. G.; Krieg, F.; Ramadan, A. J.; Patel, J. B.; Snaith, H. J.; Kovalenko, M. V.; Johnston, M. B.; Herz, L. M. CsPbBr3 nanocrystal films: deviations from bulk vibrational and optoelectronic properties. Adv. Funct. Mater. 2020, 30 (19), 1909904 (9 pp.). https://doi.org/10.1002/adfm.201909904
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Noculak, A.; Morad, V.; McCall, K. M.; Yakunin, S.; Shynkarenko, Y.; Wörle, M.; Kovalenko, M. V. Bright blue and freen luminescence of Sb(III) in double perovskite Cs2MInCl6 (M = Na, K) matrices. Chem. Mater. 2020, 32 (12), 5118-5124. https://doi.org/10.1021/acs.chemmater.0c01004
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Ochoa, M.; Buecheler, S.; Tiwari, A. N.; Carron, R. Challenges and opportunities for an efficiency boost of next generation Cu(In,Ga)Se2 solar cells: prospects for a paradigm shift. Energy Environ. Sci. 2020, 13 (7), 2047 (9 pp.). https://doi.org/10.1039/D0EE00834F
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Olaru, M.; Rychagova, E.; Ketkov, S.; Shynkarenko, Y.; Yakunin, S.; Kovalenko, M. V.; Yablonskiy, A.; Andreev, B.; Kleemiss, F.; Beckmann, J.; et al. A small cationic organo-copper cluster as thermally robust highly photo- and electro luminescent material. J. Am. Chem. Soc. 2020, 142 (1), 373-381. https://doi.org/10.1021/jacs.9b10829
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Piveteau, L.; Aebli, M.; Yazdani, N.; Millen, M.; Korosec, L.; Krieg, F.; Benin, B. M.; Morad, V.; Piveteau, C.; Shiroka, T.; et al. Bulk and nanocrystalline cesium lead-halide perovskites as seen by halide magnetic resonance. ACS Cent. Sci. 2020, 6 (7), 1138-1149. https://doi.org/10.1021/acscentsci.0c00587
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Piveteau, L.; Dirin, D. N.; Gordon, C. P.; Walder, B. J.; Ong, T. C.; Emsley, L.; Copéret, C.; Kovalenko, M. V. Colloidal-ALD-grown core/shell CdSe/CdS nanoplatelets as seen by DNP enhanced PASS-PIETA NMR spectroscopy. Nano Lett. 2020, 20 (5), 3003-3018. https://doi.org/10.1021/acs.nanolett.9b04870
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Piveteau, L.; Morad, V.; Kovalenko, M. V. Solid-state NMR and NQR spectroscopy of lead-halide perovskite materials. J. Am. Chem. Soc. 2020. https://doi.org/10.1021/jacs.0c07338
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Puppin, M.; Polishchuk, S.; Colonna, N.; Crepaldi, A.; Dirin, D. N.; Nazarenko, O.; De Gennaro, R.; Gatti, G.; Roth, S.; Barillot, T.; et al. Evidence of large polarons in photoemission band mapping of the perovskite semiconductor CsPbBr3. Phys. Rev. Lett. 2020, 124 (20), 206402 (8 pp.). https://doi.org/10.1103/PhysRevLett.124.206402
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Razera, R. A. Z.; Jacobs, D. A.; Fu, F.; Fiala, P.; Dussouillez, M.; Sahli, F.; Yang, T. C. J.; Ding, L.; Walter, A.; Feil, A. F.; et al. Instability of p-i-n perovskite solar cells under reverse bias. J. Mater. Chem. A 2020, 8 (1), 242-250. https://doi.org/10.1039/c9ta12032g
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Sasaki, E.; Dragoman, R. M.; Mantri, S.; Dirin, D. N.; Kovalenko, M. V.; Hilvert, D. Self‐assembly of proteinaceous shells around positively charged gold nanomaterials enhances colloidal stability in high ionic strength buffers. ChemBioChem 2020, 21 (1-2), 74-79. https://doi.org/10.1002/cbic.201900469
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Sastre, J.; Chen, X.; Aribia, A.; Tiwari, A. N.; Romanyuk, Y. E. Fast charge transfer across the Li7La3Zr2O12 solid electrolyte/LiCoO2 cathode interface enabled by an interphase-engineered all-thin-film architecture. ACS Appl. Mater. Interfaces 2020, 12 (32), 36196-36207. https://doi.org/10.1021/acsami.0c09777
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Sastre, J.; Priebe, A.; Döbeli, M.; Michler, J.; Tiwari, A. N.; Romanyuk, Y. E. Lithium garnet Li7La3Zr2O12 electrolyte for all-solid-state batteries: closing the gap between bulk and thin film Li-ion conductivities. Adv. Mater. Interfaces 2020, 7, 2000425 (11 pp.). https://doi.org/10.1002/admi.202000425
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All Publications

All publications of the Group can be found in Digital Object Repository at Empa - DORA