Publications 2022

Akkerman, Q. A.; Nguyen, T. P. T.; Boehme, S. C.; Montanarella, F.; Dirin, D. N.; Wechsler, P.; Beiglböck, F.; Rainò, G.; Erni, R.; Katan, C.; et al. Controlling the nucleation and growth kinetics of lead halide perovskite quantum dots. Science 2022, 377 (6613), 1406-1412. https://doi.org/10.1126/science.abq3616
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Aribia, A.; Sastre, J.; Chen, X.; Futscher, M. H.; Rumpel, M.; Priebe, A.; Döbeli, M.; Osenciat, N.; Tiwari, A. N.; Romanyuk, Y. E. Unlocking stable multi-electron cycling in NMC811 thin-films between 1.5 – 4.7 V. Adv. Energy Mater. 2022, 12 (40), 2201750 (8 pp.). https://doi.org/10.1002/aenm.202201750
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Athanasiou, M.; Manoli, A.; Papagiorgis, P.; Georgiou, K.; Berezovska, Y.; Othonos, A.; Bodnarchuk, M. I.; Kovalenko, M. V.; Itskos, G. Flexible, free-standing polymer membranes sensitized by CsPbX3 nanocrystals as gain media for low threshold, multicolor light amplification. ACS Photonics 2022. https://doi.org/10.1021/acsphotonics.2c00426
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Baumgärtner, J. F.; Krumeich, F.; Wörle, M.; Kravchyk, K. V.; Kovalenko, M. V. Thermal synthesis of conversion-type bismuth fluoride cathodes for high-energy-density Li-ion batteries. Communications Chem. 2022, 5, 6 (8 pp.). https://doi.org/10.1038/s42004-021-00622-y
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Bederak, D.; Shulga, A.; Kahmann, S.; Talsma, W.; Pelanskis, J.; Dirin, D. N.; Kovalenko, M. V.; Loi, M. A. Heterostructure from PbS quantum dot and carbon nanotube inks for high-efficiency near-infrared light-emitting field-effect transistors. Adv. Electron. Mater. 2022, 2101126 (7 pp.). https://doi.org/10.1002/aelm.202101126
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Belitsch, M.; Dirin, D. N.; Kovalenko, M. V.; Pichler, K.; Rotter, S.; Ghalgaoui, A.; Ditlbacher, H.; Hohenau, A.; Krenn, J. R. Gain and lasing from CdSe/CdS nanoplatelet stripe waveguides. Micro Nano Eng. 2022, 17, 100167 (7 pp.). https://doi.org/10.1016/j.mne.2022.100167
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Bertolotti, F.; Vivani, A.; Ferri, F.; Anzini, P.; Cervellino, A.; Bodnarchuk, M. I.; Nedelcu, G.; Bernasconi, C.; Kovalenko, M. V.; Masciocchi, N.; et al. Size segregation and atomic structural coherence in spontaneous assemblies of colloidal cesium lead halide nanocrystals. Chem. Mater. 2022, 34 (2), 594-608. https://doi.org/10.1021/acs.chemmater.1c03162
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Bolat, S.; Agiannis, E.; Yang, S. C.; Futscher, M. H.; Aribia, A.; Shorubalko, I.; Romanyuk, Y. E. Engineering bilayer AlOx /YAlOx dielectric stacks for hysteresis-free switching in solution-processed metal-oxide thin-film transistors. Front.Electron 2022, 2, 804474 (9 pp.). https://doi.org/10.3389/felec.2021.804474
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Cannelli, O.; Wiktor, J.; Colonna, N.; Leroy, L.; Puppin, M.; Bacellar, C.; Sadykov, I.; Krieg, F.; Smolentsev, G.; Kovalenko, M. V.; et al. Atomic-level description of thermal fluctuations in inorganic lead halide perovskites. J. Phys. Chem. Lett. 2022, 13 (15), 3382-3391. https://doi.org/10.1021/acs.jpclett.2c00281
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Dachraoui, W.; Bodnarchuk, M. I.; Erni, R. Direct imaging of the atomic mechanisms governing the growth and shape of bimetallic Pt-Pd nanocrystals by in situ liquid cell STEM. ACS Nano 2022, 16 (9), 14198-14209. https://doi.org/10.1021/acsnano.2c04291
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Fu, F.; Li, J.; Yang, T. C. J.; Liang, H.; Faes, A.; Jeangros, Q.; Ballif, C.; Hou, Y. Monolithic perovskite-silicon tandem solar cells: from the lab to fab? Adv. Mater. 2022, 34 (24), 2106540 (23 pp.). https://doi.org/10.1002/adma.202106540
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Fu, W.; Ricciardulli, A. G.; Akkerman, Q. A.; John, R. A.; Tavakoli, M. M.; Essig, S.; Kovalenko, M. V.; Saliba, M. Stability of perovskite materials and devices. Mater. Today 2022, 58, 275-296. https://doi.org/10.1016/j.mattod.2022.06.020
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Futscher, M. H.; Deibel, C. Defect spectroscopy in halide perovskites is dominated by ionic rather than electronic defects. ACS Energy Lett. 2022, 7, 140-144. https://doi.org/10.1021/acsenergylett.1c02076
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Futscher, M. H.; Amelal, T.; Sastre, J.; Müller, A.; Patidar, J.; Aribia, A.; Thorwarth, K.; Siol, S.; Romanyuk, Y. E. Influence of amorphous carbon interlayers on nucleation and early growth of lithium metal at the current collector-solid electrolyte interface. J. Mater. Chem. A 2022, 10 (29), 15535-15542. https://doi.org/10.1039/d2ta02843c
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Gilshtein, E.; Pfeiffer, S.; Siegrist, S.; Vlnieska, V.; Graule, T.; Romanyuk, Y. E. Photonic sintering of oxide ceramic films: effect of colored FexOy nanoparticle pigments. Ceram. 2022, 5 (3), 351-361. https://doi.org/10.3390/ceramics5030027
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Gollner, C.; Jutas, R.; Kreil, D.; Dirin, D. N.; Boehme, S. C.; Baltuška, A.; Kovalenko, M. V.; Pugžlys, A. Ultrafast electro-absorption switching in colloidal CdSe/CdS core/shell quantum dots driven by intense THz pulses. Adv. opt. mater. 2022, 10 (9), 2102407 (8 pp.). https://doi.org/10.1002/adom.202102407
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Grebenko, A. K.; Krasnikov, D. V.; Bubis, A. V.; Stolyarov, V. S.; Vyalikh, D. V.; Makarova, A. A.; Fedorov, A.; Aitkulova, A.; Alekseeva, A. A.; Gilshtein, E.; et al. High-quality graphene using boudouard reaction. Adv. Sci. 2022, 9 (12), 2200217 (12 pp.). https://doi.org/10.1002/advs.202200217
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Grimaldi, D.; Kelderer, E.; Dirin, D. N.; Kovalenko, M. V.; Hohenau, A.; Ditlbacher, H.; Krenn, J. R. Photoconductivity of PbS/perovskite quantum dots in gold nanogaps. Nanoscale Adv. 2022, 4 (17), 3566 (7 pp.). https://doi.org/10.1039/d2na00284a
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Grotevent, M. J.; Yakunin, S.; Bachmann, D.; Romero, C.; Vázquez de Aldana, J. R.; Madi, M.; Calame, M.; Kovalenko, M. V.; Shorubalko, I. Integrated photodetectors for compact Fourier-transform waveguide spectrometers. Nat. Photonics 2022. https://doi.org/10.1038/s41566-022-01088-7
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Han, K.; Sakhatskyi, K.; Jin, J.; Zhang, Q.; Kovalenko, M. V.; Xia, Z. Seed-crystal-induced cold sintering toward metal halide transparent ceramic scintillators. Adv. Mater. 2022, 34 (17), 2110420 (8 pp.). https://doi.org/10.1002/adma.202110420
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He, R.; Yi, Z.; Luo, Y.; Luo, J.; Wei, Q.; Lai, H.; Huang, H.; Zou, B.; Cui, G.; Wang, W.; et al. Pure 2D perovskite formation by interfacial engineering yields a high open-circuit voltage beyond 1.28 V for 1.77-eV wide-bandgap perovskite solar cells. Adv. Sci. 2022. https://doi.org/10.1002/advs.202203210
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Hertwig, R.; Nishiwaki, S.; Tiwari, A. N.; Carron, R. Investigation and mitigation of sputter damage on Co-evaporated Cu(In,Ga)Se2 absorbers for photovoltaic applications. Sol. RRL 2022, 6 (9), 2200268 (9 pp.). https://doi.org/10.1002/solr.202200268
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Hu, W. H.; Vael, C.; Diethelm, M.; Strassel, K.; Anantharaman, S. B.; Aribia, A.; Cremona, M.; Jenatsch, S.; Nüesch, F.; Hany, R. On the response speed of narrowband organic optical upconversion devices. Adv. opt. mater. 2022, 10 (17), 2200695 (10 pp.). https://doi.org/10.1002/adom.202200695
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Huang, C. S.; Yakunin, S.; Avaro, J.; Kang, X.; Bodnarchuk, M. I.; Liebi, M.; Sun, X.; Rossi, R. M.; Kovalenko, M. V.; Boesel, L. F. Amphiphilic polymer co-network: a versatile matrix for tailoring the photonic energy transfer in wearable energy harvesting devices. Adv. Energy Mater. 2022. https://doi.org/10.1002/aenm.202200441
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Ilatovskii, D. A.; Gilshtein, E. P.; Glukhova, O. E.; Nasibulin, A. G. Transparent conducting films based on carbon nanotubes: rational design toward the theoretical limit. Adv. Sci. 2022, 9 (24), 2201673 (16 pp.). https://doi.org/10.1002/advs.202201673
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Jiang, Y.; Lu, Z.; Zou, S.; Lai, H.; Zhang, Z.; Luo, J.; Huang, Y.; He, R.; Jin, J.; Yi, Z.; et al. Dual-site passivation of tin-related defects enabling efficient lead-free tin perovskite solar cells. Nano Energy 2022, 103, 107818 (13 pp.). https://doi.org/10.1016/j.nanoen.2022.107818
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John, R. A.; Demirağ, Y.; Shynkarenko, Y.; Berezovska, Y.; Ohannessian, N.; Payvand, M.; Zeng, P.; Bodnarchuk, M. I.; Krumeich, F.; Kara, G.; et al. Reconfigurable halide perovskite nanocrystal memristors for neuromorphic computing. Nat. Commun. 2022, 13 (1), 2074 (10 pp.). https://doi.org/10.1038/s41467-022-29727-1
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Kahmann, S.; Chen, Z.; Hordiichuk, O.; Nazarenko, O.; Shao, S.; Kovalenko, M. V.; Blake, G. R.; Tao, S.; Loi, M. A. Compositional variation in FAPb1- xSnxI3and its impact on the electronic structure: a combined density functional theory and experimental study. ACS Appl. Mater. Interfaces 2022, 14 (30), 34253-34261. https://doi.org/10.1021/acsami.2c00889
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Kirstein, E.; Yakovlev, D. R.; Glazov, M. M.; Evers, E.; Zhukov, E. A.; Belykh, V. V.; Kopteva, N. E.; Kudlacik, D.; Nazarenko, O.; Dirin, D. N.; et al. Lead-dominated hyperfine interaction impacting the carrier spin dynamics in halide perovskites. Adv. Mater. 2022, 34 (1), 2105263 (8 pp.). https://doi.org/10.1002/adma.202105263
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Kirstein, E.; Yakovlev, D. R.; Glazov, M. M.; Zhukov, E. A.; Kudlacik, D.; Kalitukha, I. V.; Sapega, V. F.; Dimitriev, G. S.; Semina, M. A.; Nestoklon, M. O.; et al. The Landé factors of electrons and holes in lead halide perovskites: universal dependence on the band gap. Nat. Commun. 2022, 13, 3062 (8 pp.). https://doi.org/10.1038/s41467-022-30701-0
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Klimpel, M.; Kovalenko, M. V.; Kravchyk, K. V. Advances and challenges of aluminum–sulfur batteries. Communications Chem. 2022, 5 (1), 77 (7 pp.). https://doi.org/10.1038/s42004-022-00693-5
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Knozowski, D.; Sasikumar, P. V. W.; Dubey, R.; Aebli, M.; Kravchyk, K. V.; Trykowski, G.; Kovalenko, M. V.; Graule, T.; Wilamowska-Zawłocka, M.; Blugan, G. Silicon oxycarbide-tin nanocomposite derived from a UV crosslinked single source preceramic precursor as high-performance anode materials for Li-ion batteries. Appl. Mater. Today 2022, 27, 101424 (10 pp.). https://doi.org/10.1016/j.apmt.2022.101424
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Kocic, J.; Dirin, D. N.; Kägi, R.; Kovalenko, M. V.; Günther, D.; Hattendorf, B. Direct analysis of nanoparticles in organic solvents by ICPMS with microdroplet injection. J. Anal. At. Spectrom. 2022, 37 (8), 1738-1750. https://doi.org/10.1039/d1ja00358e
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Kostadinov-Mutzafi, A.; Tilchin, J.; Shapiro, A.; Dirin, D. N.; Kovalenko, M. V.; Tan, L. Z.; Lifshitz, E. Impact of anisotropy in spin-orbit coupling on the magneto-optical properties of bulk lead halide perovskites. Phys. Rev. B 2022, 106 (3), 035303 (12 pp.). https://doi.org/10.1103/PhysRevB.106.035303
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Kothandaraman, R. K.; Lai, H.; Aribia, A.; Nishiwaki, S.; Siegrist, S.; Krause, M.; Zwirner, Y.; Torres Sevilla, G.; Artuk, K.; Wolff, C. M.; et al. Laser patterned flexible 4T perovskite‐Cu(In,Ga)Se2 tandem mini‐module with over 18% efficiency. Sol. RRL 2022, 6 (9), 2200392 (11 pp.). https://doi.org/10.1002/solr.202200392
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Kravchyk, K. V.; Zhang, H.; Okur, F.; Kovalenko, M. V. Li-garnet solid-state batteries with LLZO scaffolds. Acc. Mater. Res. 2022, 3 (4), 411-415. https://doi.org/10.1021/accountsmr.2c00004
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Kravchyk, K. V.; Karabay, D. T.; Kovalenko, M. V. On the feasibility of all-solid-state batteries with LLZO as a single electrolyte. Sci. Rep. 2022, 12, 1177 (10 pp.). https://doi.org/10.1038/s41598-022-05141-x
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Kravchyk, K. V.; Kovalenko, M. V. Perspective on design and technical challenges of Li-garnet solid-state batteries. Sci. Technol. Adv. Mater. 2022, 23 (1), 2018919 (8 pp.). https://doi.org/10.1080/14686996.2021.2018919
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Lai, H.; Luo, J.; Zwirner, Y.; Olthof, S.; Wieczorek, A.; Ye, F.; Jeangros, Q.; Yin, X.; Akhundova, F.; Ma, T.; et al. High-performance flexible all-perovskite tandem solar cells with reduced VOC-deficit in wide-bandgap subcell. Adv. Energy Mater. 2022, 12 (45), 2202438 (12 pp.). https://doi.org/10.1002/aenm.202202438
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Mikhaylov, A.; Zakharova, M.; Vlnieska, V.; Khanda, A.; Bremer, S.; Zuber, M.; Pezzin, S. H.; Kunka, D. Inverted Hartmann mask made by deep X-ray lithography for single-shot multi-contrast X-ray imaging with laboratory setup. Opt. Express 2022, 30 (6), 8494-8509. https://doi.org/10.1364/OE.452114
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Milanese, S.; De Giorgi, M. L.; Cerdán, L.; La-Placa, M. G.; Jamaludin, N. F.; Bruno, A.; Bolink, H. J.; Kovalenko, M. V.; Anni, M. Amplified spontaneous emission threshold dependence on determination method in dye-doped polymer and lead halide perovskite waveguides. Molecules 2022, 27 (13), 4261 (15 pp.). https://doi.org/10.3390/molecules27134261
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Montanarella, F.; Kovalenko, M. V. Three millennia of nanocrystals. ACS Nano 2022, 16 (4), 5085-5102. https://doi.org/10.1021/acsnano.1c11159
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Moser, T.; Kothandaraman, R.; Yang, S.; Walter, A.; Siegrist, S.; Lai, H.; Gilshtein, E.; Tiwari, A. N.; Fu, F. Understanding the formation process of perovskite layers grown by chemical vapour deposition. Front. Energy Res. 2022, 10, 883882 (11 pp.). https://doi.org/10.3389/fenrg.2022.883882
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Munoz-Diaz, L.; Rosa, A. J.; Bou, A.; Sánchez, R. S.; Romero, B.; John, R. A.; Kovalenko, M. V.; Guerrero, A.; Bisquert, J. Inductive and capacitive hysteresis of halide perovskite solar cells and memristors under illumination. Front. Energy Res. 2022, 10, 914115. https://doi.org/10.3389/fenrg.2022.914115
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Ochoa, M.; Yang, S. C.; Nishiwaki, S.; Tiwari, A. N.; Carron, R. Charge carrier lifetime fluctuations and performance evaluation of Cu(In,Ga)Se2 absorbers via time-resolved-photoluminescence microscopy. Adv. Energy Mater. 2022, 12 (3), 2102800 (12 pp.). https://doi.org/10.1002/aenm.202102800
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Ossig, C.; Pyrlik, N.; Carron, R.; Fevola, G.; Patjens, S.; Strelow, C.; Flügge, J.; Kolditz, A.; Siebels, J.; Garrevoet, J.; et al. X-ray vision of Cu(In,Ga)Se2: From the Ga/In ratio to solar-cell performance. J. Phys. Energy 2022, 4 (4), 045007 (11 pp.). https://doi.org/10.1088/2515-7655/ac9256
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Polishchuk, S.; Puppin, M.; Crepaldi, A.; Gatti, G.; Dirin, D. N.; Nazarenko, O.; Colonna, N.; Marzari, N.; Kovalenko, M. V.; Grioni, M.; et al. Nanoscale-resolved surface-to-bulk electron transport in CsPbBr3Perovskite. Nano Lett. 2022, 22 (3), 1067-1074. https://doi.org/10.1021/acs.nanolett.1c03941
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Rainò, G.; Kovalenko, M. V. Locking exciton fine-structure splitting. Nat. Mater. 2022. https://doi.org/10.1038/s41563-022-01372-5
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Rainò, G.; Yazdani, N.; Boehme, S. C.; Kober-Czerny, M.; Zhu, C.; Krieg, F.; Rossell, M. D.; Erni, R.; Wood, V.; Infante, I.; et al. Ultra-narrow room-temperature emission from single CsPbBr3 perovskite quantum dots. Nat. Commun. 2022, 13, 2587 (8 pp.). https://doi.org/10.1038/s41467-022-30016-0
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Reber, D.; Borodin, O.; Becker, M.; Rentsch, D.; Thienenkamp, J. H.; Grissa, R.; Zhao, W.; Aribia, A.; Brunklaus, G.; Battaglia, C.; et al. Water/ionic liquid/succinonitrile hybrid electrolytes for aqueous batteries. Adv. Funct. Mater. 2022, 32 (20), 2112138 (13 pp.). https://doi.org/10.1002/adfm.202112138
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All Publications

All publications of the Group can be found in Digital Object Repository at Empa - DORA