Publications 2023

Zhang, H.; Dubey, R.; Inniger, M.; Okur, F.; Wullich, R.; Parrilli, A.; Karabay, D. T.; Neels, A.; Kravchyk, K. V.; Kovalenko, M. V. Ultrafast-sintered self-standing LLZO membranes for high energy density lithium-garnet solid-state batteries. Cell Rep. Phys. Sci. 2023, 4 (7), 101473 (15 pp.). https://doi.org/10.1016/j.xcrp.2023.101473
Detailed Record
Kirstein, E.; Smirnov, D. S.; Zhukov, E. A.; Yakovlev, D. R.; Kopteva, N. E.; Dirin, D. N.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M. The squeezed dark nuclear spin state in lead halide perovskites. Nat. Commun. 2023, 14 (1), 6683 (8 pp.). https://doi.org/10.1038/s41467-023-42265-8
Detailed Record
Tamarat, P.; Prin, E.; Berezovska, Y.; Moskalenko, A.; Nguyen, T. P. T.; Xia, C.; Hou, L.; Trebbia, J. B.; Zacharias, M.; Pedesseau, L.; et al. Universal scaling laws for charge-carrier interactions with quantum confinement in lead-halide perovskites. Nat. Commun. 2023, 14, 229 (8 pp.). https://doi.org/10.1038/s41467-023-35842-4
Detailed Record
Anghel, S.; Poshakinskiy, A. V.; Yakovlev, D. R.; Kirstein, E.; Kopteva, N. E.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M.; Betz, M. Fast diffusion of spin polarized excitons in organic-inorganic lead halide perovskites. ACS Photonics 2023, 10, 4169-4176. https://doi.org/10.1021/acsphotonics.3c00891
Detailed Record
Anzini, P.; Biganzoli, D.; Cherniukh, I.; Kovalenko, M. V.; Parola, A.; Ferri, F. Variance analysis of dynamic light scattering data. Rev. Sci. Instrum. 2023, 94 (9), 095117 (11 pp.). https://doi.org/10.1063/5.0161845
Detailed Record
Müller, A.; Okur, F.; Aribia, A.; Osenciat, N.; Vaz, C. A. F.; Siller, V.; El Kazzi, M.; Gilshtein, E.; Futscher, M. H.; Kravchyk, K. V.; et al. Benchmarking the performance of lithiated metal oxide interlayers at the LiCoO2|LLZO interface. Mater. Adv. 2023, 4 (9), 2138-2146. https://doi.org/10.1039/d3ma00155e
Detailed Record
Kravchyk, K. V.; Kovalenko, M. V. On achievable gravimetric and volumetric energy densities of Al dual-ion batteries. ACS Energy Lett. 2023, 8 (2), 1266-1269. https://doi.org/10.1021/acsenergylett.2c02908
Detailed Record
Boumenou, C. K.; Phirke, H.; Rommelfangen, J.; Audinot, J. N.; Nishiwaki, S.; Wirtz, T.; Carron, R.; Redinger, A. Nanoscale surface analysis reveals origins of enhanced interface passivation in RbF post deposition treated CIGSe solar cells. Adv. Funct. Mater. 2023, 33 (30), 2300590 (15 pp.). https://doi.org/10.1002/adfm.202300590
Detailed Record
Limantoro, C.; Das, T.; He, M.; Dirin, D.; Manos, J.; Kovalenko, M. V.; Chrzanowski, W. Synthesis of antimicrobial gallium nanoparticles using the hot injection method. ACS Mater. Au 2023, 3 (4), 310-320. https://doi.org/10.1021/acsmaterialsau.2c00078
Detailed Record
Grisard, S.; Trifonov, A. V.; Solovev, I. A.; Yakovlev, D. R.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M.; Akimov, I. A. Long-lived exciton coherence in mixed-halide perovskite crystals. Nano Lett. 2023, 23 (16), 7397-7403. https://doi.org/10.1021/acs.nanolett.3c01817
Detailed Record
Häusermann, D.; Bodry, S.; Wiesemüller, F.; Miriyev, A.; Siegrist, S.; Fu, F.; Gaan, S.; Koebel, M. M.; Malfait, W. J.; Zhao, S.; et al. FireDrone: multi-environment thermally agnostic aerial robot. Adv. Intell. Syst. 2023, 5 (9), 2300101 (11 pp.). https://doi.org/10.1002/aisy.202300101
Detailed Record
Nette, J.; Montanarella, F.; Zhu, C.; Sekh, T. V.; Boehme, S. C.; Bodnarchuk, M. I.; Rainò, G.; Howes, P. D.; Kovalenko, M. V.; deMello, A. J. Microfluidic synthesis of monodisperse and size-tunable CsPbBr3 supraparticles. Chem. Commun. 2023, 59, 3554 (4 pp.). https://doi.org/10.1039/d3cc00093a
Detailed Record
Kara, G.; Bolat, S.; Sharma, K.; Grotevent, M. J.; Dirin, D. N.; Bachmann, D.; Furrer, R.; Boesel, L. F.; Romanyuk, Y. E.; Rossi, R. M.; et al. Conformal integration of an inkjet‐printed PbS QDs‐graphene IR photodetector on a polymer optical fiber. Adv. Mater. Technol. 2023, 8 (9), 2201922 (11 pp.). https://doi.org/10.1002/admt.202201922
Detailed Record
Zhang, H.; Okur, F.; Cancellieri, C.; Jeurgens, L. P. H.; Parrilli, A.; Karabay, D. T.; Nesvadba, M.; Hwang, S.; Neels, A.; Kovalenko, M. V.; et al. Bilayer dense‐porous Li7La3Zr2O12 membranes for high‐performance Li‐garnet solid‐state batteries. Adv. Sci. 2023, 10 (8), 2205821 (10 pp.). https://doi.org/10.1002/advs.202205821
Detailed Record
Zhang, H.; Paggiaro, G.; Okur, F.; Huwiler, J.; Cancellieri, C.; Jeurgens, L. P. H.; Chernyshov, D.; Van Beek, W.; Kovalenko, M. V.; Kravchyk, K. V. On high-temperature thermal cleaning of Li7La3Zr2O12 solid-state electrolytes. ACS Appl. Energy Mater. 2023, 6 (13), 6972-6980. https://doi.org/10.1021/acsaem.3c00459
Detailed Record
Tan, H. Q.; Liang, H.; Krause, M.; Zhao, X.; Kothandaraman, R.; Carron, R.; Tiwari, A. N.; Fu, F.; Birgersson, E.; Hou, Y.; et al. Accounting for fabrication variability in transparent perovskite solar cells for four-terminal tandem applications. Sol. RRL 2023, 7 (18), 2300339 (13 pp.). https://doi.org/10.1002/solr.202300339
Detailed Record
Milanese, S.; Morello, G.; De Giorgi, M. L.; Cretì, A.; Andrusiv, H.; Bodnarchuk, M. I.; Qualtieri, A.; Lomascolo, M.; Kovalenko, M. V.; Anni, M. Air-sensitive amplified spontaneous emission in lecithin-capped CsPbBr3 nanocrystals thin films. Mater. Today Phys. 2023, 35, 101098 (8 pp.). https://doi.org/10.1016/j.mtphys.2023.101098
Detailed Record
Aebli, M.; Kaul, C. J.; Yazdani, N.; Krieg, F.; Bernasconi, C.; Guggisberg, D.; Marczak, M.; Morad, V.; Piveteau, L.; Bodnarchuk, M. I.; et al. Disorder and halide distributions in cesium lead halide nanocrystals as seen by colloidal 133Cs nuclear magnetic resonance spectroscopy. Chem. Mater. 2023, 36 (6), 2599-3054. https://doi.org/10.1021/acs.chemmater.3c02901
Detailed Record
Liu, S.; Becker, M.; Huang-Joos, Y.; Lai, H.; Homann, G.; Grissa, R.; Egorov, K.; Fu, F.; Battaglia, C.; Kühnel, R. S. Multifunctional additive ethoxy(pentafluoro)cyclotriphosphazene enables safe carbonate electrolyte for SiOx-graphite/NMC811 batteries. Batter. Supercaps 2023, 6 (7), e202300220 (10 pp.). https://doi.org/10.1002/batt.202300220
Detailed Record
Wieczorek, A.; Lai, H.; Pious, J.; Fu, F.; Siol, S. Resolving oxidation states and X–site composition of Sn perovskites through Auger parameter analysis in XPS. Adv. Mater. Interfaces 2023, 10 (7), 2201828 (7 pp.). https://doi.org/10.1002/admi.202201828
Detailed Record
Warby, J.; Shah, S.; Thiesbrummel, J.; Gutierrez-Partida, E.; Lai, H.; Alebachew, B.; Grischek, M.; Yang, F.; Lang, F.; Albrecht, S.; et al. Mismatch of quasi–fermi level splitting and Voc in perovskite solar cells. Adv. Energy Mater. 2023, 13 (48), 2303135 (12 pp.). https://doi.org/10.1002/aenm.202303135
Detailed Record
Zhang, Z.; Huang, Y.; Wang, C.; Jiang, Y.; Jin, J.; Xu, J.; Li, Z.; Su, Z.; Zhou, Q.; Zhu, J.; et al. Green-antisolvent-regulated distribution of p-type self-doping enables tin perovskite solar cells with an efficiency of over 14%. Energy Environ. Sci. 2023, 16 (8), 3430-3440. https://doi.org/10.1039/d3ee00601h
Detailed Record
Kurisinkal Pious, J.; Zwirner, Y.; Lai, H.; Olthof, S.; Jeangros, Q.; Gilshtein, E.; Kothandaraman, R. K.; Artuk, K.; Wechsler, P.; Chen, C.; et al. Revealing the role of tin fluoride additive in narrow bandgap Pb-Sn perovskites for highly efficient flexible all-perovskite tandem cells. ACS Appl. Mater. Interfaces 2023, 15 (7), 10151-10157. https://doi.org/10.1021/acsami.2c19124
Detailed Record
Seiler, H.; Zahn, D.; Taylor, V. C. A.; Bodnarchuk, M. I.; Windsor, Y. W.; Kovalenko, M. V.; Ernstorfer, R. Direct observation of ultrafast lattice distortions during exciton-polaron formation in lead halide perovskite nanocrystals. ACS Nano 2023, 17 (3), 1979-1988. https://doi.org/10.1021/acsnano.2c06727
Detailed Record
Siegrist, S.; Nandi, P.; Kothandaraman, R. K.; Abdessalem, A.; Tiwari, A. N.; Fu, F. Understanding coating thickness and uniformity of blade-coated SnO2 electron transport layer for scalable perovskite solar cells. Sol. RRL 2023, 7 (14), 2300273 (7 pp.). https://doi.org/10.1002/solr.202300273
Detailed Record
Harkort, C.; Kudlacik, D.; Kopteva, N. E.; Yakovlev, D. R.; Karzel, M.; Kirstein, E.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M. Spin-flip raman scattering on electrons and holes in two-dimensional (PEA)2PbI4 perovskites. Small 2023, 19 (32), 2300988 (10 pp.). https://doi.org/10.1002/smll.202300988
Detailed Record
Kumaar, D.; Can, M.; Portner, K.; Weigand, H.; Yarema, O.; Wintersteller, S.; Schenk, F.; Boskovic, D.; Pharizat, N.; Meinert, R.; et al. Colloidal ternary telluride quantum dots for tunable phase change optics in the visible and near-infrared. ACS Nano 2023, 17 (7), 6985-6997. https://doi.org/10.1021/acsnano.3c01187
Detailed Record
Krause, M.; Yang, S. C.; Moser, S.; Nishiwaki, S.; Tiwari, A. N.; Carron, R. Silver-alloyed low-bandgap CuInSe2 solar cells for tandem applications. Sol. RRL 2023, 7 (9), 2201122 (10 pp.). https://doi.org/10.1002/solr.202201122
Detailed Record
Zhu, C.; Nguyen, T.; Boehme, S. C.; Moskalenko, A.; Dirin, D. N.; Bodnarchuk, M. I.; Katan, C.; Even, J.; Rainò, G.; Kovalenko, M. V. Many-body correlations and exciton complexes in CsPbBr3 quantum dots. Adv. Mater. 2023, 35 (9), 2208354 (9 pp.). https://doi.org/10.1002/adma.202208354
Detailed Record
Strandell, D.; Dirin, D.; Zenatti, D.; Nagpal, P.; Ghosh, A.; Raino, G.; Kovalenko, M. V.; Kambhampati, P. Enhancing multiexcitonic emission in metal-halide perovskites by quantum confinement. ACS Nano 2023, 17 (24), 24910-24918. https://doi.org/10.1021/acsnano.3c06497
Detailed Record
Tonkaev, P.; Grechaninova, E.; Iorsh, I.; Montanarella, F.; Kivshar, Y.; Kovalenko, M. V.; Makarov, S. Multiscale supercrystal meta-atoms. Nano Lett. 2023, 24, 2758-2764. https://doi.org/10.1021/acs.nanolett.3c04580
Detailed Record
Welty, C.; Taylor, E. E.; Posey, S.; Vailati, P.; Kravchyk, K. V.; Kovalenko, M. V.; Stadie, N. P. Methodological studies of the mechanism of anion insertion in nanometer-sized carbon micropores. ChemSusChem 2023, 16 (4), e202201847 (11 pp.). https://doi.org/10.1002/cssc.202201847
Detailed Record
Priebe, A.; Aribia, A.; Sastre, J.; Romanyuk, Y. E.; Michler, J. 3D high-resolution chemical characterization of sputtered Li-rich NMC811 thin films using TOF-SIMS. Anal. Chem. 2023, 95 (2), 1074-1084. https://doi.org/10.1021/acs.analchem.2c03780
Detailed Record
Kopteva, N. E.; Yakovlev, D. R.; Kirstein, E.; Zhukov, E. A.; Kudlacik, D.; Kalitukha, I. V.; Sapega, V. F.; Hordiichuk, O.; Dirin, D. N.; Kovalenko, M. V.; et al. Weak dispersion of exciton Landé factor with band gap energy in lead halide perovskites: approximate compensation of the electron and hole dependences. Small 2023. https://doi.org/10.1002/smll.202300935
Detailed Record
Kirstein, E.; Zhukov, E. A.; Yakovlev, D. R.; Kopteva, N. E.; Harkort, C.; Kudlacik, D.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M. Coherent spin dynamics of electrons in two-dimensional (PEA)2PbI4 perovskites. Nano Lett. 2023, 23 (1), 205-212. https://doi.org/10.1021/acs.nanolett.2c03975
Detailed Record
Hallstrom, J.; Cherniukh, I.; Zha, X.; Kovalenko, M. V.; Travesset, A. Ligand effects in assembly of cubic and spherical nanocrystals: applications to packing of perovskite nanocubes. ACS Nano 2023, 17 (8), 7219-7228. https://doi.org/10.1021/acsnano.2c10079
Detailed Record
Dirin, D. N.; Vivani, A.; Zacharias, M.; Sekh, T. V.; Cherniukh, I.; Yakunin, S.; Bertolotti, F.; Aebli, M.; Schaller, R. D.; Wieczorek, A.; et al. Intrinsic formamidinium tin iodide nanocrystals by suppressing the Sn(IV) impurities. Nano Lett. 2023, 23, 1914-1923. https://doi.org/10.1021/acs.nanolett.2c04927
Detailed Record
Futscher, M. H.; Brinkman, L.; Müller, A.; Casella, J.; Aribia, A.; Romanyuk, Y. E. Monolithically-stacked thin-film solid-state batteries. Communications Chem. 2023, 6 (1), 110 (7 pp.). https://doi.org/10.1038/s42004-023-00901-w
Detailed Record
Bojar, A.; Micha, D.; Giteau, M.; Ruiz-Preciado, M. A.; Paetzold, U. W.; Simor, M.; Gevaerts, V. S.; Carron, R.; Medjoubi, K.; Collin, S.; et al. Optical simulations and optimization of perovskite/CI(G)S tandem solar cells using the transfer matrix method. J. Phys. Energy 2023, 5 (3), 035001 (12 pp.). https://doi.org/10.1088/2515-7655/accf34
Detailed Record
Carwithen, B. P.; Hopper, T. R.; Ge, Z.; Mondal, N.; Wang, T.; Mazlumian, R.; Zheng, X.; Krieg, F.; Montanarella, F.; Nedelcu, G.; et al. Confinement and exciton binding energy effects on hot carrier cooling in lead halide perovskite nanomaterials. ACS Nano 2023, 17 (7), 6638-6648. https://doi.org/10.1021/acsnano.2c12373
Detailed Record
Klimpel, M.; Zhang, H.; Kovalenko, M. V.; Kravchyk, K. V. Standardizing critical current density measurements in lithium garnets. Communications Chem. 2023, 6 (1), 192 (3 pp.). https://doi.org/10.1038/s42004-023-01002-4
Detailed Record
Baumgärtner, J. F.; Wörle, M.; Guntlin, C. P.; Krumeich, F.; Siegrist, S.; Vogt, V.; Stoian, D. C.; Chernyshov, D.; van Beek, W.; Kravchyk, K. V.; et al. Pyrochlore‐type iron hydroxy fluorides as low‐cost lithium‐ion cathode materials for stationary energy storage. Adv. Mater. 2023, 35 (49), 2304158 (11 pp.). https://doi.org/10.1002/adma.202304158
Detailed Record
Liang, H.; Feng, J.; Rodríguez-Gallegos, C. D.; Krause, M.; Wang, X.; Alvianto, E.; Guo, R.; Liu, H.; Kothandaraman, R. K.; Carron, R.; et al. 29.9%-efficient, commercially viable perovskite/CuInSe2 thin-film tandem solar cells. Joule 2023, 7 (12), 2859-2872. https://doi.org/10.1016/j.joule.2023.10.007
Detailed Record
Yang, Y.; Zhao, T.; Li, M. H.; Wu, X.; Han, M.; Yang, S. C.; Xu, Q.; Xian, L.; Chi, X.; Zhao, N. J.; et al. Passivation of positively charged cationic defects in perovskite with nitrogen-donor crown ether enabling efficient perovskite solar cells. Chem. Eng. J. 2023, 451, 138962 (9 pp.). https://doi.org/10.1016/j.cej.2022.138962
Detailed Record
Shrivastava, M.; Krieg, F.; Kovalenko, M. V.; Adarsh, K. V. Photon-dressed biexciton-mediated anomalous optical Stark effect in CsPbBr3 nanocrystals. Surf. Interface Anal. 2023, 55 (6-7), 501-506. https://doi.org/10.1002/sia.7153
Detailed Record
He, R.; Wang, W.; Yi, Z.; Lang, F.; Chen, C.; Luo, J.; Zhu, J.; Thiesbrummel, J.; Shah, S.; Wei, K.; et al. Improving interface quality for 1-cm2 all-perovskite tandem solar cells. Nature 2023, 618 (7963), 80-86. https://doi.org/10.1038/s41586-023-05992-y
Detailed Record
Luo, J.; He, R.; Lai, H.; Chen, C.; Zhu, J.; Xu, Y.; Yao, F.; Ma, T.; Luo, Y.; Yi, Z.; et al. Improved carrier management via a multifunctional modifier for high-quality low-bandgap Sn–Pb perovskites and rfficient sll-perovskite tandem solar cells. Adv. Mater. 2023, 35 (22), 2300352 (11 pp.). https://doi.org/10.1002/adma.202300352
Detailed Record
Sakhatskyi, K.; Turedi, B.; Matt, G. J.; Wu, E.; Sakhatska, A.; Bartosh, V.; Lintangpradipto, M. N.; Naphade, R.; Shorubalko, I.; Mohammed, O. F.; et al. Stable perovskite single-crystal X-ray imaging detectors with single-photon sensitivity. Nat. Photonics 2023, 17, 510-517. https://doi.org/10.1038/s41566-023-01207-y
Detailed Record
Zhao, W.; Wang, K.; Dubey, R.; Ren, F.; Brack, E.; Becker, M.; Grissa, R.; Seidl, L.; Pagani, F.; Egorov, K.; et al. Extending the high-voltage operation of graphite/NCM811 cells by constructing a robust electrode/electrolyte interphase layer. Mater. Today Energy 2023, 34, 101301 (11 pp.). https://doi.org/10.1016/j.mtener.2023.101301
Detailed Record
Yang, S. C.; Lin, T. Y.; Ochoa, M.; Lai, H.; Kothandaraman, R.; Fu, F.; Tiwari, A. N.; Carron, R. Efficiency boost of bifacial Cu(In,Ga)Se2 thin-film solar cells for flexible and tandem applications with silver-assisted low-temperature process. Nat. Energy 2023, 8, 40-51. https://doi.org/10.1038/s41560-022-01157-9
Detailed Record

All Publications

All publications of the Group can be found in Digital Object Repository at Empa - DORA